铁红环氧酯涂层中缓蚀剂的研究

在有机涂层中加入缓蚀剂构成耐蚀涂层,可以进一步提高原涂层的耐蚀能力。本文研究了一种缓蚀剂HN(由H和N复配而成,H为杂环类,N为胺类),用在普通涂层—铁红环氧酯中试验。采用了四种方法:电化学交流阻抗法,盐雾箱试验法,人造海水浸泡,海上实船挂片,并分别与未加缓蚀剂的原涂层进行对比,对各涂层的耐蚀性能进行评定。结果表明:在铁红环氧酯中加入少量HN缓蚀剂后,在不改变原涂层附着力的情况下,明显提高了原涂层的耐蚀能力。     

聚氨酯防腐涂料综述

介绍了聚氨酯防腐涂料的种类、成分及其性能,并与现有的防腐涂料进行了比较。     

活性粉末混凝土200（RPC200）的配制试验研究

进行了活性粉末混凝土(RPC)的配制试验,通过5批试件分别探讨砂灰比、石英粉、硅灰、水胶比和钢纤维等因素单值变化时对RPC流动度以及抗折强度、抗压强度的影响.研究表明:在常规制作工艺条件下,配制出抗压强度和抗折强度分别为145.6 MPa和26.68MPa的无纤维RPC;当钢纤维含量为6%时,RPC的抗压强度和抗折强度分别达到了201.3MPa和73.67 MPa.     

碳化硼涂覆的碳纤维的抗热氧化性研究

用自己合成的裂解能得到碳化硼的聚碳硼烷,对碳纤维进行涂层,并详细测试了涂层碳纤维的抗热氧化性能。     

氮气保护法在微细铝粉生产中的应用

雾化空气法生产微细铝粉已有近 70年历史 ,但其生产过程极易发生爆炸 ,氮气由于其良好的防火性能 ,在生产中代替空气将会极大降低爆炸的可能性。     

湿热环境中油罐防腐设计

湿热环境中油罐的腐蚀主要体现为电化学腐蚀的特征，适宜的防腐措施对提高油罐的建设质量，减缓油罐的腐蚀速度，延长油罐的使用寿命，减小维护费用等具有积极的意义。从分析湿热环境中油罐腐蚀规律出发，介绍了油罐内外壁防腐涂层的选用原则，对3000m^3地面立式油罐的牺牲阳极电法保护进行了设计计算，提出了施工方法，对湿热环境中油罐防腐具有指导意义。     

A quasi-isentropic model of a cylinder driven by aluminized explosives based on characteristic line analysis

A quasi-isentropic study on the process of driving a cylinder with aluminized explosives was carried out to examine the influence of the aluminum (Al) reaction rate on cylinder expansion and the physical parameters of the detonation products. Based on the proposed quasi-isentropic hypothesis and relevant isentropic theories, the characteristic lines of aluminized explosives driving a cylinder were analyzed, and a quasi-isentropic model was established. This model includes the variation of the cylinder wall velocity and the physical parameters of the detonation products with the Al reaction degree. Using previously reported experimental results, the quasi-isentropic model was verified to be applicative and accurate. This model was used to calculate the physical parameters for cylinder experiments with aluminized cyclotrimethylenetrinitramine explosives with 15.0 % and 30.0 % Al content. The results show that this quasi-isentropic model can be used not only to calculate the cylinder expansion rule or Al reaction degree, but also to calculate the physical parameters of the detonation products in the process of cylinder expansion. For explosives with 15.0 % and 30.0 % Al, 24.3 % and 18.5 % of the Al was found to have reacted at 33.9 μs and 34.0 μs, respectively. The difference in Al content results in different reaction intensity, occurrence time, and duration of two forms of reaction (diffusion and kinetic) between the Al powder and the detonation products; the post-detonation burning reaction between the Al powder and the detonation products prolongs the positive pressure action time, resulting in a continuous rise in temperature after detonation.     

Preparation and characterization of HMX/NH2-GO composite with enhanced thermal safety and desensitization

To improve the safety of HMX, HMX/NH₂-GO composite was prepared with aqueous ammonia functionalized graphene oxide (NH₂-GO). The composite was characterized by SEM, Zeta potential, XPS, Raman spectrum, XRD, HPLC, DSC and BAM sensitivity test. The results indicated that the functionalization with aqueous ammonia can enhance the interaction between GO and HMX, and more efficiently desensitize the explosive. The optimal impact sensitivity of the HMX/NH₂-GO composite can be not less than 40 J, which is also the most insensitivity compared to the previous reports prepared by coating desensitization with non-energetic desensitized material. Moreover, the potential reason for the different impact and friction sensitivity was also discussed, which may bring a novel perspective to achieve the desensitization of energetic material.     

火炮发射药装药自动识别方法

发射装药号是影响火炮身管寿命的重要因素,为自动识别火炮发射药的装药号,避免人工记录失误和完善火炮射弹履历,分析了装药号自动识别原理,运用火炮动力学分析理论和ADAMS虚拟样机技术,建立火炮发射动力学虚拟样机.通过仿真试验获取样本数据,应用BP神经网络进行学习和训练,从而建立装药号和测试数据之间的非线性映射关系,实现对火炮发射装药号的精确预测.     

Damage analysis of POZD coated square reinforced concrete slab under contact blast

High efficiency, environmental protection and sustainability have become the main theme of the development of the protection engineering, requiring that the components not only meet the basic functions, but also have chemical properties such as acid and alkali corrosion resistance and aging resistance. Polyisocyanate-oxazodone (POZD) polymer has the above characteristics, it also has the advantages of strong toughness, high strength and high elongation. The concrete slab sprayed with POZD material has excellent anti-blast performance. In order to explore the damage characteristics of POZD sprayed concrete slabs under the action of contact explosion thoroughly, the contact explosion test of POZD concrete slabs with different charges were carried out. On the basis of experimental verification, numerical simulation were used to study the influence of the thickness of the POZD on the blast resistance of the concrete slab. According to the test and numerical simulation results that as the thickness of the coating increases, the anti-blast performance of the concrete slab gradually increases, and the TNT equivalent required for critical failure is larger. Based on the above analysis, empirical expressions on normalized crater diameter, the normalized spall diameter and normalized spall diameter are obtained.